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Synthesis of Azasugars via Lanthanide-Promoted Aza Diels−Alder Reactions in Aqueous Solution

✍ Scribed by Yu, Libing; Li, Jun; Ramirez, Johnny; Chen, Depu; Wang, Peng George


Book ID
125967752
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
276 KB
Volume
62
Category
Article
ISSN
0022-3263

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Asymmetric synthesis of bicyclic amino a
✍ Waldmann, Herbert ;Braun, Matthias 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 372 KB

## Abstract Derivatives 7–10 and 13–16 of methyl and ethyl 2‐azabicyclo[2.2.1]heptane‐3‐carboxylates are synthesized by Aza‐Diels‐Alder reactions of chiral iminium ions, formed in situ from glyoxylic acid and chiral amines, with cyclopentadiene. Whereas the heterodienophiles derived from phenylglyc