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Electro-organic reactions. Part 52: Diels–Alder reactions in aqueous solution via electrogenerated quinodimethanes

✍ Scribed by James H.P Utley; Erada Oguntoye; Carmen Z Smith; Peter B Wyatt

Book ID
108379962
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
224 KB
Volume
41
Category
Article
ISSN
0040-4039

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Electro-organic reactions. Part 46. Diel
Electro-organic reactions. Part 46. Diels-Alder trapping of o-quinodimethane generated by redox-mediated cathodic reduction of α,α′-dibromo-o-xylene in the presence of hindered dienophiles
✍ Erada Oguntoye (neéEru); Sabine Szunerits; James H.P Utley; Peter B Wyatt 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 424 KB

Hindered, electron-deficient alkenes 5-11 have been prepared, including analogues of maleic anhydride, Nphenylmaleimide and benzoquinone. Cyclic voltammetry showed that most of these compounds can undergo reduction to form relatively persistent radical-anions, which can mediate the reductive cleavag