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Retro-Diels−Alder Reaction in Aqueous Solution: Toward a Better Understanding of Organic Reactivity in Water

✍ Scribed by Wijnen, Jan W.; Engberts, Jan B. F. N.


Book ID
126271878
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
270 KB
Volume
62
Category
Article
ISSN
0022-3263

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A Hetero Retro Diels–Alder Reaction in A
✍ Wijnen, Jan W. ;Engberts, Jan B. F. N. 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 439 KB

## Abstract The adduct of the Diels–Alder reaction of nitrosobenzene with cyclopentadiene is not stable in solution. The equilibrium constant for the reaction depends strongly on the medium and water induces a spectacular shift to the adduct. Comparison with the bimolecular addition of nitrosobenze