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Understanding the high reactivity of triazolinediones in Diels-Alder reactions. A DFT study

✍ Scribed by Fernández-Herrera, María A.; Zavala-Oseguera, Claudia; Cabellos, José Luis; Sandoval-Ramírez, Jesús; Domingo, Luis R.; Merino, Gabriel


Book ID
121866129
Publisher
Springer-Verlag
Year
2014
Tongue
English
Weight
468 KB
Volume
20
Category
Article
ISSN
1610-2940

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endo-exo Selectivity in Diels-Alder cycloadditions of several o-quinodimethanes (1-4) with acrylonitrile, 2-(5H)-furanone and N-methylmaleimide has been investigated in acetonitrile solution. Transition structures of the cycloaddition of the parent o-QDM (1), (E,E)-1,8-dimethyl-o-QDM (2), isoindene