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Aza Diels-Alder reactions in aqueous solution: cyclocondensation of dienes with simple iminium salts generated under Mannich conditions

✍ Scribed by Larsen, Scott D.; Grieco, Paul A.

Book ID
111915890
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
263 KB
Volume
107
Category
Article
ISSN
0002-7863

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Brønsted acid-catalyzed aza Diels-Alder reaction of Danishefsky's diene with aldimine generated in situ from aldehyde and amine in aqueous media
✍ Takahiko Akiyama; Jun Takaya; Hirotaka Kagoshima 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 197 KB

Three-component aza Diels-Alder reaction, starting from aldehyde, aniline, and Danishefsky's diene, took place smoothly under the influence of HBF4 in aqueous media to afford dihydro-4-pyridone derivatives in high yields.