Asymmetric synthesis of bicyclic amino a
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Waldmann, Herbert ;Braun, Matthias
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Article
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1991
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John Wiley and Sons
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English
⚖ 372 KB
## Abstract Derivatives 7–10 and 13–16 of methyl and ethyl 2‐azabicyclo[2.2.1]heptane‐3‐carboxylates are synthesized by Aza‐Diels‐Alder reactions of chiral iminium ions, formed in situ from glyoxylic acid and chiral amines, with cyclopentadiene. Whereas the heterodienophiles derived from phenylglyc