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Amino Acid Methyl Esters as Chiral Auxiliaries in Aza–Diels-Alder Reactions in Aqueous Solution

✍ Scribed by Dr. Herbert Waldmann


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
239 KB
Volume
27
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Asymmetric synthesis of bicyclic amino a
✍ Waldmann, Herbert ;Braun, Matthias 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 372 KB

## Abstract Derivatives 7–10 and 13–16 of methyl and ethyl 2‐azabicyclo[2.2.1]heptane‐3‐carboxylates are synthesized by Aza‐Diels‐Alder reactions of chiral iminium ions, formed in situ from glyoxylic acid and chiral amines, with cyclopentadiene. Whereas the heterodienophiles derived from phenylglyc