Synthesis of acrylic esters by lipase
β Scribed by Isao Ikeda; Jun Tanaka; Kimihiro Suzuki
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 128 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
A simple synthesis of sugar fatty acid esters was developed in a nonaqueous solution using lipase modified by synthetic detergent. Esterification of sugar was accelerated by continuous removal of water from the reaction mixture with a molecular sieve. When glucose and palmitic acid (1:1 by mole) wer
Monomethoxypolyethylene glycols (PEG) of molecular masses 1900 and 5000 were activated using p-nitrophenyl chloroformate to form PEGnitrophenyl carbonates (activated PEG) with high yield (96-98%). The activated PEG was covalently attached to Candida rugosa lipase. Increasing the molar ratio of activ
Novoaym 435 -a commercially available immobilized lipase from Candida antarctica -shows an activity for the transesteritication using acrylic or methacrylic methylester as solvent and as acylating agent superior to all other enzymes tested. This transesterification is very fast compared to other enz
Short chain fatty acid esters of geraniol and citronellol WCR synthesized by lipase-catalyzed transesterification with yields as high as 98% molar conversion. Triacylglycerols were the best substrates and immohili~edCf/nrlitfri tmturcticu lipase, SP435 gave the highest overall yields. The lipases te