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Synthesis of sugar fatty acid esters by modified lipase

✍ Scribed by Wakako Tsuzuki; Yoshiaki Kitamura; Tateo Suzuki; Shoichi Kobayashi

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 77 KB
Volume: 64
Category: Article
ISSN: 0006-3592
DOI: 10.1002/(sici)1097-0290(19990805)64:3<267::aid-bit2>3.0.co;2-b

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✦ Synopsis

A simple synthesis of sugar fatty acid esters was developed in a nonaqueous solution using lipase modified by synthetic detergent. Esterification of sugar was accelerated by continuous removal of water from the reaction mixture with a molecular sieve. When glucose and palmitic acid (1:1 by mole) were used as the starting substrates, more than 90% of glucose was converted to its ester in this system. The resultant product was 6-O-palmitoylglucose. Other mono-or disaccharides were also esterified by the modified lipase with high yield. It was shown that the modified lipase might act as a catalyst for the synthesis of sugar fatty acid esters.

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