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An efficient method for lipase-catalysed preparation of acrylic and methacrylic acid esters

✍ Scribed by Siegfried Warwel; Georg Steinke; Mark Rüsch gen. Klaas

Publisher: Springer-Verlag
Year: 1996
Tongue: English
Weight: 297 KB
Volume: 10
Category: Article
ISSN: 0951-208X
DOI: 10.1007/bf00184030

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✦ Synopsis

Novoaym 435 -a commercially available immobilized lipase from Candida antarctica -shows an activity for the transesteritication using acrylic or methacrylic methylester as solvent and as acylating agent superior to all other enzymes tested. This transesterification is very fast compared to other enzyme-catalysed reactions (1.5 h). Novel acrylic and methacrylic esters from unsaturated fatty alcohols can be prepared this way in yields of 65 to 94 % and under mild conditions (30 'C, atmospheric pressure).

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