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Synthesis of a chiral tricyclo[5.2.1.02.6]-deca-4,8-dien-3-one

โœ Scribed by Zhi-Yu Liu; Jian Zhang


Book ID
112060329
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
183 KB
Volume
13
Category
Article
ISSN
0256-7660

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ChemInform Abstract: Asymmetric Desymmet
โœ F. J. A. D. BAKKEREN; N. G. RAMESH; D. DE GROOT; A. J. H. KLUNDER; B. ZWANENBURG ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

## Asymmetric Desymmetrization of a Pseudo-meso endo-Tricyclo(5.2.1.02,6) deca-4,8-dien-3-one by Chiral Amines. -The title compound (I) undergoes a dynamic kinetic resolution to enaminones (III) applying prolinol or its methyl ether as chiral mediators. Reductive elimination of the chiral auxilia