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Electronic control of stereoselectivity. 7. Stereospecificity of N-methyltriazolinedione cycloaddition to tricyclo[5.2.1.02,6]deca-2,5-diene, tricyclo[5.2.1.02,6]deca-2,5,8-triene, and tricyclo[5.2.2.02,6]undeca-2,5,8-triene

โœ Scribed by Paquette, Leo A.; Carr, Richard V. C.; Charumilind, Pana; Blount, John F.


Book ID
115491889
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
698 KB
Volume
45
Category
Article
ISSN
0022-3263

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Electronic control of stereoselectivity.
โœ Leh-Yeh Hsu; Susan J. Hathaway; Leo A. Paquette ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 214 KB

the effect of all, due to the customary greater importance of d,-$, interactions relative to those of the c',-Q1 type. In this event, a metallic species with contracted dT orbitals (i.e., a small metal or one in a high oxidation state) would likely favor top-side bonding (viz., z), whereas one with