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Photoisomerization of Tricyclo[5.2.1.04.10]deca-2,5,8-triene (Triquinacene)

✍ Scribed by Dipl.-Chem. Dieter Bosse; Doz. Dr. Armin de Meijere

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
249 KB
Volume
13
Category
Article
ISSN
0044-8249

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Bridgehead Cations of Tricyclo[5.2.1.04, 10]deca-2,5,8-triene (Triquinacene)
✍ Dr. Dieter Bosse; Prof. Dr. Armin de Meijere 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 231 KB

imentally determined activation energy for the 1,2 hydride shift on the 2-norbornyl cation is 10 kcal/mol[q. These relative energy predictions have now been confirmed e~perimentalIy[~l. The calculated flattening of the carbenium ion into an almost planar divinylcarbenium ion is supported by the 'Ha