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Syntheses of the tricyclo[5.2.1.04,8]deca-2,5-diene system

โœ Scribed by H. Bos; G. Ellen; G.W. Klumpp; J.J. Vrielink

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
156 KB
Volume
14
Category
Article
ISSN
0040-4039

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โœ Dr. Dieter Bosse; Prof. Dr. Armin de Meijere ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 231 KB

imentally determined activation energy for the 1,2 hydride shift on the 2-norbornyl cation is 10 kcal/mol[q. These relative energy predictions have now been confirmed e~perimentalIy[~l. The calculated flattening of the carbenium ion into an almost planar divinylcarbenium ion is supported by the 'Ha