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Redox behavior of ferrocene derivatives. 2. Bis(.eta.5-tricyclo[5.2.1.02,6]deca-2,5,8-trien-6-yl)iron and related molecules

✍ Scribed by Gallucci, Judith C.; Opromolla, Giuliana; Paquette, Leo A.; Pardi, Luca; Schirch, Paulo F. T.; Sivik, Mark R.; Zanello, Piero


Book ID
124094716
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
661 KB
Volume
32
Category
Article
ISSN
0020-1669

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the effect of all, due to the customary greater importance of d,-$, interactions relative to those of the c',-Q1 type. In this event, a metallic species with contracted dT orbitals (i.e., a small metal or one in a high oxidation state) would likely favor top-side bonding (viz., z), whereas one with