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Bis(.eta.5-tricyclo[5.2.1.02,6]deca-2,5,8-trien-4-yl) derivatives of the Group IV transition metals

โœ Scribed by Bhide, Vinayak V.; Rinaldi, Peter L.; Farona, Michael F.


Book ID
126805959
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
545 KB
Volume
9
Category
Article
ISSN
0276-7333

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Electronic control of stereoselectivity.
โœ Leh-Yeh Hsu; Susan J. Hathaway; Leo A. Paquette ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 214 KB

the effect of all, due to the customary greater importance of d,-$, interactions relative to those of the c',-Q1 type. In this event, a metallic species with contracted dT orbitals (i.e., a small metal or one in a high oxidation state) would likely favor top-side bonding (viz., z), whereas one with