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Metal hydride reductions of endo-tricyclo[5.2.1.02,6]deca-4,8-dien-3-one (endo-dicyclopentadienone)

✍ Scribed by Dilling, Wendell L.; Plepys, Raymond A.

Book ID: 125838336
Publisher: American Chemical Society
Year: 1970
Tongue: English
Weight: 884 KB
Volume: 35
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00834a026

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## Asymmetric Desymmetrization of a Pseudo-meso endo-Tricyclo(5.2.1.02,6) deca-4,8-dien-3-one by Chiral Amines. -The title compound (I) undergoes a dynamic kinetic resolution to enaminones (III) applying prolinol or its methyl ether as chiral mediators. Reductive elimination of the chiral auxilia