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Synthesis of [4-14C]-pelargonidin chloride and [4-14C]-delphinidin chloride

✍ Scribed by Michael Kraus; Ellen Biskup; Elke Richling; Peter Schreier

Publisher: John Wiley and Sons
Year: 2006
Tongue: French
Weight: 157 KB
Volume: 49
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.1120

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✦ Synopsis

The synthesis of [4-14 C]-pelargonidin chloride and [4-14 C]-delphinidin chloride via [formyl-14 C]-2-(benzoyloxy)-4,6-dihydroxybenzaldehyde, o,4-diacetoxyacetophenone and o,3,4,5-tetraacetoxyacetophenone is described. The first step comprised labelling of the carbonyl group of 2-(benzoyloxy)-4,6-dihydroxybenzaldehyde, verifying that the coupling with o,4-diacetoxyacetophenone or o,3,4,5-tetraacetoxyacetophenone under hydrogen chloride atmosphere resulted in the formation of [4-14 C] labelled anthocyanidins.

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