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Synthesis of 3′-deoxynucleosides II. Synthesis of 9-(3-deoxyaldofuranosyl) adenines derived from 3-deoxy-D-glucose

✍ Scribed by D. H. Murray; J. Prokop


Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
607 KB
Volume
54
Category
Article
ISSN
0022-3549

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Synthesis of deoxy sugars I. New synthes
✍ Daniel H. Murray; J. Prokop 📂 Article 📅 1965 🏛 John Wiley and Sons 🌐 English ⚖ 340 KB

Condensation of Z-deoxy-~-ribose with nitromethane gave, after deionization, a syrupy mixture of epimeric l-nitro-1,3-dideoxy-hexitols. Acid hydrolysis under Nef reaction conditions produced a mixture of 3-deoxy-~-glucose and 3-deoxy-m mannose, separable by cellulose chromatography or fractional cry