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Synthesis of 2H-1,2,3-Triazolo[4,5-c][1,2,4]triazolo[4,3-a]-pyridines and Related Systems

✍ Scribed by Sukumar Varma, K. ;Havaldar, Freddy ;Nanavati, Shrenik ;Patel, Bomi ;Fernandes, Peter S.


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
270 KB
Volume
1985
Category
Article
ISSN
0947-3440

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✦ Synopsis


Synthese von 2H-1,2,3-Triazolo[4,5-~][1,2,4]triazolo[4,3-a]pyridinen und verwandten Systemen Zur Herstellung des 2H-1,2,3-Triazolo[4,5-c]pyridin-4(5H)-ons 4 wurde 2-Phenyl-2H-l,2,3triazol-4-carbaldehyd (1) zunichst in die Acrylsiiure 2 umgewandelt und letztere dann nach vorausgehender Curtius-Umlagerung des Saureazids 3 thermisch cyclisiert. Das Pyridinon 4 wurde in sein Hydrazino-Derivat 8 umgewandelt und nach zwei verschiedenen Methoden durch Reaktion mit geeigneten Carbonsauren sowie Acetylaceton zu der im Titel genannten Verbindung vom Typ 9 sowie zu 10 umgesetzt.


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