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Synthesis of 2,4,6-tri-t-butylthiobenzaldehyde, the first stable thiobenzaldehyde

โœ Scribed by Okazaki, Renji; Ishii, Akihiko; Fukuda, Nobuo; Oyama, Hiroyuki; Inamoto, Neoki


Book ID
120823208
Publisher
The Royal Society of Chemistry
Year
1982
Tongue
English
Weight
144 KB
Volume
20
Category
Article
ISSN
0022-4936

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The first rotational isomers of thiobenzaldehydes, TbtCH=S (2a and 2b: Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl), were synthesized and isolated as stable crystalline compounds by the desulfurization of the corresponding overcrowded cyclic polysulfides TbtCHS, (n = 5 or 8) with phosphine rea