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Photocycloaddition reactions of the first stable thioaldehyde: 2,4,6-tri(tert-butyl)thiobenzaldehyde with substituted allenes

โœ Scribed by G. Hofstra; J. Kamphuis; H.J.T. Bos


Book ID
104232497
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
230 KB
Volume
25
Category
Article
ISSN
0040-4039

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Synthesis, Structure, and Reactions of t
โœ Nobuhiro Takeda; Prof. Dr. Norihiro Tokitoh; Prof. Dr. Renji Okazaki ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 996 KB

The first rotational isomers of thiobenzaldehydes, TbtCH=S (2a and 2b: Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl), were synthesized and isolated as stable crystalline compounds by the desulfurization of the corresponding overcrowded cyclic polysulfides TbtCHS, (n = 5 or 8) with phosphine rea