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Thermal and photochemical reactions of a stable thiobenzaldehyde, 2,4,6-tri-t-butylthiobenzaldehyde

✍ Scribed by Renji Okazaki; Akihiko Ishii; Nobuo Fukuda; Hiroyuki Oyama; Naoki Inamoto

Book ID: 104232491
Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 200 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80044-7

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✦ Synopsis

Thermal and photochemical reactions of the title compound gave benzothiolane g in high yield; the reaction with free radicals also afforded 2 along with some other products.

We have recently reported the synthesisof the first stable thiobenzaldehyde, 2,4,6-tri-t-butylthiobenzaldehyde (L).' The ready availability and thermal stability of & enable us to study the chemical reactivities of the thioaldehyde about which only little has been known so far.

2 3 Recent papers on some reactions of thioaldehydes prompted us to report our preliminary results

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