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Synthesis and Structure of 2,4,6-Tris[bis(trimethylsilyl)methyl]thiobenzaldehyde: The First Isolation of Rotational Isomers of Thiobenzaldehydes

โœ Scribed by Tokitoh, Norihiro; Takeda, Nobuhiro; Okazaki, Renji


Book ID
127316144
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
254 KB
Volume
116
Category
Article
ISSN
0002-7863

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Synthesis, Structure, and Reactions of t
โœ Nobuhiro Takeda; Prof. Dr. Norihiro Tokitoh; Prof. Dr. Renji Okazaki ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 996 KB

The first rotational isomers of thiobenzaldehydes, TbtCH=S (2a and 2b: Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl), were synthesized and isolated as stable crystalline compounds by the desulfurization of the corresponding overcrowded cyclic polysulfides TbtCHS, (n = 5 or 8) with phosphine rea