Synthesis, Structure, and Reactions of t
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Nobuhiro Takeda; Prof. Dr. Norihiro Tokitoh; Prof. Dr. Renji Okazaki
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Article
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1997
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John Wiley and Sons
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English
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The first rotational isomers of thiobenzaldehydes, TbtCH=S (2a and 2b: Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl), were synthesized and isolated as stable crystalline compounds by the desulfurization of the corresponding overcrowded cyclic polysulfides TbtCHS, (n = 5 or 8) with phosphine rea