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Synthesis of 2-iodo-4,5-dimethylphosphinine and its conversion to organometallic derivatives

✍ Scribed by Herman T. Teunissen; Friedrich Bickelhaupt

Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
139 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis

The synthesis of the title compound I via a halophosphaalkenclDicls Alder route is &scribed. Conversion of 1 to the corresponding zinc derivative 7 as well as conversion of the tungsten complex 6 to the lithium cqund

9 allows funtionalisation of the phosphinine system at the 2-position.

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