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Synthesis of 1,4-diketones by the reaction of silyl enol ether with silver oxide. Regiospecific formation of silver(I) enolate intermediates

✍ Scribed by Ito, Yoshihiko; Konoike, Toshiro; Saegusa, Takeo


Book ID
121321393
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
349 KB
Volume
97
Category
Article
ISSN
0002-7863

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Synthesis of 1,4-diketones by the coupli
✍ Robert M. Moriarty; Raju Penmasta; Indra Prakash πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 183 KB

Synthesis of 1,4-diketones in good yields was achieved by the coupling reaction of the trinethylsilyl enol ethers of acetophenone, thiophene or furan with lead tetraacetate in dry dichloromethane and tetrahydrofuran at -78"C.