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Synthesis of 1,4-diketones by the coupling reaction of trimethylsilyl enol ethers with lead tetraacetate

✍ Scribed by Robert M. Moriarty; Raju Penmasta; Indra Prakash

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 183 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81011-x

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✦ Synopsis

Synthesis of 1,4-diketones in good yields was achieved by the coupling reaction of the trinethylsilyl enol ethers of acetophenone, thiophene or furan with lead tetraacetate in dry dichloromethane and tetrahydrofuran at -78"C.

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