✦ LIBER ✦

Facile synthesis of silyl enol ethers by Mg-promoted coupling of aliphatic carbonyl compounds with trimethylsilyl chloride

✍ Scribed by Yoshio Ishino; Yoshio Kita; Hirofumi Maekawa; Toshinobu Ohno; Yasuhiro Yamasaki; Toshiyuki Miyata; Ikuzo Nishiguchi

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 225 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)02659-8

No coin nor oath required. For personal study only.

✦ Synopsis

Treatment of aliphatic carbonyl compounds with trimethyisilyl chloride with Mg turning for Grignard reaction without any pre-treatmem in N,N-dimethylformamide at room temperature brought about highly facile, effective and stereoselective coupling to give the corresponding silyl enol ethers in good yields.

📜 SIMILAR VOLUMES

ChemInform Abstract: Facile Synthesis of

ChemInform Abstract: Facile Synthesis of Silyl Enol Ethers by Mg-Promoted Coupling of Aliphatic Carbonyl Compounds with Trimethylsilyl Chloride.

✍ Yoshio Ishino; Yoshio Kita; Hirofumi Maekawa; Toshinobu Ohno; Yasuhiro Yamasaki; 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

Mg-Promoted Reductive Coupling of Aromat

Mg-Promoted Reductive Coupling of Aromatic Carbonyl Compounds with Trimethylsilyl Chloride and Bis(chlorodimethylsilyl) Compounds.

✍ Tetsuro Uchida; Yoshio Kita; Hirofumi Maekawa; Ikuzo Nishiguchi 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

ChemInform Abstract: Synthesis of Optica

ChemInform Abstract: Synthesis of Optically Active α-Hydroxy Carbonyl Compounds by the Catalytic, Enantioselective Oxidation of Silyl Enol Ethers and Ketene Acetals with (Salen)manganese(III) Complexes.

✍ W. ADAM; R. T. FELL; V. R. STEGMANN; C. R. SAHA-MOELLER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 1 views