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ChemInform Abstract: Synthesis of (.+-.)-Stemonamide by the Application of Oxidative Coupling Reactions of Stannyl Compounds with Silyl Enol Ethers.

โœ Scribed by Y. KOHNO; K. NARASAKA


Book ID
112039012
Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
27
Category
Article
ISSN
0931-7597

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Treatment of aliphatic carbonyl compounds with trimethyisilyl chloride with Mg turning for Grignard reaction without any pre-treatmem in N,N-dimethylformamide at room temperature brought about highly facile, effective and stereoselective coupling to give the corresponding silyl enol ethers in good y