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Synthesis of (1,213C)-2-chloroethyl phenyl sulfide

✍ Scribed by Douglass F. Taber; Yanong Wang

Publisher
John Wiley and Sons
Year
1995
Tongue
French
Weight
260 KB
Volume
36
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

Incorporation of a double ^13^C label into the mustard 2‐chloroethyl phenyl sulfide 2 is straightforward, but analysis is complicated by ^13^C‐^13^C coupling. An alternative is reported, in which the ease of scrambling of sulfur mustards is used to advantage to prepare precisely 50% (1, 2‐^13^C) enriched 2, with each carbon of the ethyl chain labelled to provide optimal signal to noise in the ^13^C spectrum.

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