Synthesis, crystal structure and magnetic properties of new indium rhenium and scandium rhenium oxides, In6ReO12 and Sc6ReO12
β Scribed by D. Mikhailova; H. Ehrenberg; H. Fuess
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 338 KB
- Volume
- 179
- Category
- Article
- ISSN
- 0022-4596
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Compounds of the series Ln 6 ReO 12 , Lnβ«Ψβ¬Ho, Er, Tm, Yb, and Lu, have been prepared by subsolidus reaction and are isotypic with Ln 6 MoO 12 , Ln 6 WO 12 , and Ln 6 UO 12 , crystallizing in space group R3 with Zβ«3Ψβ¬ for the R-centered setting. The magnetic moment per rhenium ion in Lu 6 ReO 12 is
One-dimensional compounds Ca 3 CoRhO 6 and Ca 3 FeRhO 6 have been newly synthesized and structurally characterized by Rietveld re5nement of powder X-ray di4raction data. Both compounds are isostructural with the rhombohedral K 4 CdCl 6 -type structure (space group R3 c; Z