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Synthesis, molecular structure and magnetic properties of a rhenium(IV) compound with catechol

✍ Scribed by A. Cuevas; L. Geis; V. Pintos; R. Chiozzone; J. Sanchíz; M. Hummert; H. Schumann; C. Kremer

Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
379 KB
Volume
921
Category
Article
ISSN
0022-2860

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✍ Winfried Plass 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 657 KB

The aminoalcohol ligands diethanolamine (H 2 dea) and triethanolamine (H 3 tea) react with [VO(acac) 2 ] to yield the tetranuclear oxovanadium(IV) complexes [{VO(dea)} 2 -{VO(acac)} 2 (µ 2 -OMe) 2 ] (1) and [{VO(Htea)} 2 {VO(acac)} 2 (µ 2 -OMe) 2 ] (2). In the case of the potentially bridging aminoa