Synthesis conditions, crystal structures, and magnetic properties of quasi-one-dimensional complex oxides Ca 3 CuMnO 6 (space group P-1, z โซุโฌ 4, triclinic cell) and Ca 3 Co 1ุx Mn 1ุx O 6 with x โซุโฌ 0, 0.25, 1.0 (structural type K 4 CdCl 6 , space group R-3c, z โซุโฌ 6) are presented. The crystal str
Synthesis, Crystal Structure, and Magnetic Properties of New One-Dimensional Oxides Ca3CoRhO6 and Ca3FeRhO6
โ Scribed by Seiji Niitaka; Hiroshi Kageyama; Masaki Kato; Kazuyoshi Yoshimura; Koji Kosuge
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 243 KB
- Volume
- 146
- Category
- Article
- ISSN
- 0022-4596
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โฆ Synopsis
One-dimensional compounds Ca 3 CoRhO 6 and Ca 3 FeRhO 6 have been newly synthesized and structurally characterized by Rietveld re5nement of powder X-ray di4raction data. Both compounds are isostructural with the rhombohedral K 4 CdCl 6 -type structure (space group R3 c; Z
๐ SIMILAR VOLUMES
New one-dimensional compounds Ca 3 CoBO 6 (B โซุโฌ Ir, Ru) with K 4 CdCl 6 -type structure have been synthesized by conventional solid state reactions. Both compounds adopt the rhombohedral symmetry with the space group R3 c; a โซุโฌ 9.1811(1) A s , c โซุโฌ 10.8232(3) A s , Z โซุโฌ 6 (hexagonal expression)