Synthesis, crystal structure and configuration of acetylated aryl Pyrogallol[4]arenes
โ Scribed by Jun Han; Xiaokai Song; Li Liu; Chaoguo Yan
- Book ID
- 106388972
- Publisher
- Springer Netherlands
- Year
- 2007
- Tongue
- English
- Weight
- 528 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0923-0750
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A series of resorcin [4]arene and pyrogallol[4]arene macrocycles have been synthesized efficiently within 5 min, affording crystalline products suitable for single crystal X-ray diffraction, utilising microwave irradiation in a 'one-pot' reaction whilst controlling the selective formation of the rcc
The acid-catalyzed condensation of pyrogallol and aldehydes yields pyrogallol[4]arenes, which associate in the form of hexameric capsules of extraordinary stability due to the presence of 48 intermolecular hydrogen bonds seaming the individual pyrogallol[4]arenes together.