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Crystal and Molecular Structure of Calix[4]arene Originating from Pyrogallol

✍ Scribed by A. T. Gubaidullin; I. L. Nikolaeva; A. R. Burilov; I. A. Litvinov; M. A. Pudovik; W. D. Habicher; A. I. Konovalov


Book ID
110311671
Publisher
Springer
Year
2001
Tongue
English
Weight
91 KB
Volume
71
Category
Article
ISSN
1070-3632

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## Abstract We first make use of aminolysis of calix[4]arene esters to synthesize calix[4]arene amides. When the two ethyl esters of the calix[4]arene esters are aminolysized, the 1, 3‐amide derivative is formed selectively. The crystal structures of the calix‐[4] arene with two butyl amide (3b) an

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## Abstract Four __p‐tert__‐butylcalix[4]arene derivatives with different Schiff base groups at the lower rim were efficiently prepared in three steps. __p‐tert__‐Butylcalix[4]arene was firstly __O‐__peralkylated with __Ο‰__‐haloalkylphthalimide in the system of NaH/DMF to give calixarene tetraalkyl