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On the synthesis and structure of the very large spherical capsules derived from hexamers of pyrogallol[4]arenes

✍ Scribed by Jerry L Atwood; Leonard J Barbour; Agoston Jerga

Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 326 KB
Volume: 1
Category: Article
ISSN: 1472-7862
DOI: 10.1016/s1472-7862(02)00003-5

No coin nor oath required. For personal study only.

✦ Synopsis

The acid-catalyzed condensation of pyrogallol and aldehydes yields pyrogallol[4]arenes, which associate in the form of hexameric capsules of extraordinary stability due to the presence of 48 intermolecular hydrogen bonds seaming the individual pyrogallol[4]arenes together.

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