Synthesis, Characterization and X-Ray Structure of Bis(O-propyldithiocarbonato-κ2S,S′)bis(4-cyanopyridine-κN)nickel(II)
✍ Scribed by Sanjay Kapoor; Renu Sachar; Kuldeep Singh; Vivek K. Gupta; Rajnikant
- Book ID
- 113070418
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 419 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1572-8854
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📜 SIMILAR VOLUMES
The Ni atom in the linear polymeric title complex, [Ni{S~2~P(OC~6~H~11~)~2~}~2~(NC~5~H~4~C~5~H~4~N)]~__n__~ or [Ni(C~12~H~22~O~2~PS~2~)~2~(C~10~H~8~N~2~)]~__n__~, is octahedrally coordinated within a __trans__-N~2~S~4~ donor set. The Ni atom and the N atoms of the 4,4′-bipyridine ligand are located
The Ni atom in the zigzag polymeric title complex, [Ni(C~4~H~7~OS~2~)~2~(C~12~H~12~N~2~)]~__n__~, is situated on a twofold axis and the bridging ligand situated about a centre of inversion. The structure features a distorted octahedral __cis__-NiN~2~S~4~ coordination geometry defined by two chelatin