The Ni atom in the linear polymeric title complex, [Ni{S~2~P(OC~6~H~11~)~2~}~2~(NC~5~H~4~C~5~H~4~N)]~__n__~ or [Ni(C~12~H~22~O~2~PS~2~)~2~(C~10~H~8~N~2~)]~__n__~, is octahedrally coordinated within a __trans__-N~2~S~4~ donor set. The Ni atom and the N atoms of the 4,4′-bipyridine ligand are located
catena-Poly[[[bis[(−)-O-bornyldithiocarbonato-κ2S,S′]nickel(II)]-μ-4,4′-bipyridine-κ2N:N′] chloroform disolvate]
✍ Scribed by Dakternieks, Dainis ;Duthie, Andrew ;Lai, Chian-Sing ;Tiekink, Edward R. T.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 467 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the title complex, [Cu(C 7 H 4 ClO 2 ) 2 (C 10 H 8 N 2 )] n , the Cu II ion, lying on an inversion centre, is coordinated by two monodentate 4-chlorobenzoate ligands and two N atoms from two bridging 4,4 0 -bipyridine ligands, each disposed about a centre of inversion, within an N 2 O 2 square pl
The title compound, [Cd(C 2 H 6 O 2 PS 2 ) 2 (C 10 H 8 N 2 )] n , contains zigzag chains linked through the 4,4 H -bipyridine groups. The Cd atom exhibits a slightly distorted octahedral coordination environment, consisting of four S atoms of the chelating dimethyl dithiophosphate ligands and two N