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Synthesis and transannular diels-alder reaction of a trans-cis-cis 13-membered macrocyclic trienono

✍ Scribed by Kurt Baettig; Anne Marinier; Rita Pitteloud; Pierre Deslongchamps


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
149 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis


Upon heating at 300%. TCC trienone 14 gave tricyclic ketone 15.


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Synthesis of chiral trans-syn-cis and tr
✍ Rico Lavoie; AndrΓ‘s TorΓ³; Pierre Deslongchamps πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 892 KB

Stereocontrolled asymmetric synthesis and transannular Diels-Alder (TADA) reaction of a 14-membered transcis-cis (TCC) macrocyclic trienone with an activated dienophile leading to an A.B.C [6.6.6] tricycle having one angular methyl group is reported. The results of thermal and Lewis acid catalyzed T