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Synthesis and transannular diels-alder reaction of a 13-membered macrocyclic triene having a tetrasubstituted enol ether as a dienophile

✍ Scribed by Gervais Bérubé; Pierre Deslongchamps

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 280 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96701-7

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✦ Synopsis

Cyclization of TTC aliylic chloride 22 gave TTC macrocycle 24 which was directly converted into a mixture of tricycles TST 25 and CSC 26.

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