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Synthesis and transannular diels-alder reaction of a cis-trans-trans 13-membered macrocyclic trienone

✍ Scribed by Kurt Baettig; Carol Dallaire; Rita Pitteloud; Pierre Deslongchamps

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 294 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96699-1

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✦ Synopsis

Upon heating at 3OO"C, C77 macrocyclic trienone 17 underwent 1,5-H shift and/or transannular DiebAlder yielding three tricyciic isomers 18, 19, and 20.

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