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ChemInform Abstract: Unique trans-syn-cis [6.6.7] Tricycle Derivative from Transannular Diels—Alder Contraction of a Model 15-Membered trans-cis-cis Macrocyclic Triene.

✍ Scribed by M. DROUIN; D. G. HALL; A.-S. CAILLE; P. DESLONGCHAMPS


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Transannular Diels—
✍ L. BARRIAULT; S. G. OUELLET; P. DESLONGCHAMPS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Transannular Diels-Alder Reaction Studies with an Activated Dienophile. An Enantioselective Synthesis of an A.B.C.[6.6.6.] trans-syn-cis Tricycle. -The synthesis of the chiral macrocycle (VI) starting from nerol (I), and its transannular Diels-Alder reaction (TADA) under thermal conditions affordi