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Synthesis and structures of germanium-containing tungsten carbyne complexes Ph3gec≡w(ch2but)3and Ph3GeC≡W(CH2SiMe3)3

✍ Scribed by A. V. Safronova; L. N. Bochkarev; N. E. Stolyarova; I. K. Grigorieva; I. P. Malysheva; G. V. Basova; G. K. Fukin; E. V. Baranov; Yu. A. Kurskii; G. A. Abakumov


Book ID
106520029
Publisher
Springer
Year
2006
Tongue
English
Weight
272 KB
Volume
55
Category
Article
ISSN
1573-9171

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## Abstract The reaction of lithium phenyl(trimethylsilyl)methanide with phenyl(trimethylsilyl)methylzinc chloride‐tmeda in the presence of tmeda yields the addition product, a bis(tmeda)‐lithium dialkylchlorozincate. The elimination of lithium chloride leads to the formation of a tmeda adduct of b