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Synthesis and Structures of Crystalline Lithium, Sodium, Potassium, and Magnesium Silylmethyls Derived from the Ligands [CH(SiMe 3 ){SiMe 3- n (OMe) n }] - ( n = 1, 2), [CH(SiMe 2 OMe) 2 ] - , and [CH(SiMe 3 )(SiMe 2 Ph)] -

✍ Scribed by Antolini, Floria; Hitchcock, Peter B.; Lappert, Michael F.; Wei, Xue-Hong


Book ID
127390160
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
309 KB
Volume
22
Category
Article
ISSN
0276-7333

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## Abstract The reaction of lithium phenyl(trimethylsilyl)methanide with phenyl(trimethylsilyl)methylzinc chloride‐tmeda in the presence of tmeda yields the addition product, a bis(tmeda)‐lithium dialkylchlorozincate. The elimination of lithium chloride leads to the formation of a tmeda adduct of b