## Abstract Both amido‐(cyclopentadienyl)boranes and bis(cyclopentadienyl)boranes of the types R~2~NB(C~__x__~H~__y__~) (NR′) and R~2~NB(C~__x__~H~__y__~)~2~ (R = alkyl, trimethylsilyl; R′ = Ph; C~__x__~H~__y__~ = C~5~H~5~ (cyclopentadienyl), C~9~H~7~ (indenyl), C~13~H~9~ (fluorenyl)) were recently
✦ LIBER ✦
Synthesis and Structures of Alkali Metal Amides Derived from the Ligands [N(SiMe2Ph)(SiMe3)]−, [N(tBu)(SiMe3)]−, [N(Ph)(2-C5H4N)]−, and [N(2-C5H4N)2]−
✍ Scribed by Floria Antolini; Peter B. Hitchcock; Alexei V. Khvostov; Michael F. Lappert
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 251 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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The silanediols RN(SiMe3)Si(OSiMe3)(0H)2 (R = 2,4,6-were characterized by means of mass, IR and NMR (lH and Me3C6H2 4, 2,6-Me2C6H3 5 , and 2,6-iPr2C6H3 6) were prepa-2gSi) spectroscopy. Additionally, the molecular structures of red by the reactions of the respective silanetriols RN(SiMe3)-4 and 7 we