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Chelate Complexes with Aliphatic Tripodal Triisocyanide Ligands: Synthesis and Crystal Structures of fac-{[HC(CH2CH2CH2NC)3]W(CO)3}, fac-{[N(CH2CH2CH2NC)3]W(CO)3}, and the Dimer fac,fac-{[N(CH2CH2CH2NC)3]W(CO)3}2

✍ Scribed by Hahn, F. Ekkehardt; Tamm, Matthias


Book ID
127357913
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
866 KB
Volume
13
Category
Article
ISSN
0276-7333

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Coordinatedversus Noncoordinated Isocyan
✍ Ekkehardt Hahn, F. ;Tamm, Matthias πŸ“‚ Article πŸ“… 1992 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 246 KB πŸ‘ 1 views

The triisocyanide ligand CH3C(CH2NC)3 reacts with Cr-acterized by an X-ray structure analysis allowing a direct com-(CO),(THF) depending on the stoichiometry to give the com-parison of the bonding parameters of coordinated and nonplexes CH3C(CH2NC),[CH2NC ~ Cr(C0)5]3-, (x = 1, 2). The coordinated is