18-Crown-6 and Titanium Tetrafluoride โ
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T.ย Stanley Cameron; Andreas Decken; Evgenyย G. Ilyin; Grigoriย B. Nikiforov; Jack
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Article
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2004
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John Wiley and Sons
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English
โ 181 KB
๐ 1 views
## Abstract Reaction of TiF~4~ and 18โcrownโ6 in MeCN affords the molecular complex [(__cisโ__TiF~4~)~2~(18โcrownโ6)] (1) only. Water and THF displace the 18โcrownโ6 in the tetrafluoro complex 1, with the formation of __cisโ__TiF~4~L~2~. The complex __cisโ__TiF~4~(H~2~O)~2~ and 18โcrownโ6 form [{__