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Crown ether complexes of actinide elements an X-ray study of the conformational change of the crown ether within the UO2(NO3)2(H2O)2(18-crown-6) molecule

✍ Scribed by G. Bombieri; G. De Paoli; A. Immirzi


Book ID
115975139
Publisher
Elsevier Science
Year
1978
Weight
277 KB
Volume
40
Category
Article
ISSN
0022-1902

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18-Crown-6 and Titanium Tetrafluoride βˆ’
✍ T.Β Stanley Cameron; Andreas Decken; EvgenyΒ G. Ilyin; GrigoriΒ B. Nikiforov; Jack πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 181 KB πŸ‘ 1 views

## Abstract Reaction of TiF~4~ and 18‐crown‐6 in MeCN affords the molecular complex [(__cis‐__TiF~4~)~2~(18‐crown‐6)] (1) only. Water and THF displace the 18‐crown‐6 in the tetrafluoro complex 1, with the formation of __cis‐__TiF~4~L~2~. The complex __cis‐__TiF~4~(H~2~O)~2~ and 18‐crown‐6 form [{__