𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and structure of (H2O·HBF4)2(18-crown-6)

✍ Scribed by Jerry L. Atwood; Abbas Alvanipour; Hongming Zhang

Publisher
Springer
Year
1992
Tongue
English
Weight
225 KB
Volume
22
Category
Article
ISSN
1572-8854

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Crystal structure of ZnCl2·H2O·18-crown-
Crystal structure of ZnCl2·H2O·18-crown-6
✍ V. K. Bel'skii; L. V. Ivakina; N. R. Strel'tsova; P. A. Storozhenko; B. M. Bulyc 📂 Article 📅 1990 🏛 SP MAIK Nauka/Interperiodica 🌐 English ⚖ 169 KB
18-Crown-6 and Titanium Tetrafluoride −
18-Crown-6 and Titanium Tetrafluoride − Preparation of the TiIV Fluoride Crown Ether Complexes (TiF4)2(18-Crown-6) and the Stabilization of cis-TiF4(H2O)2 in [{cis-TiF4(H2O)2}2(18-Crown-6)]
✍ T. Stanley Cameron; Andreas Decken; Evgeny G. Ilyin; Grigori B. Nikiforov; Jack 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB 👁 1 views

## Abstract Reaction of TiF~4~ and 18‐crown‐6 in MeCN affords the molecular complex [(__cis‐__TiF~4~)~2~(18‐crown‐6)] (1) only. Water and THF displace the 18‐crown‐6 in the tetrafluoro complex 1, with the formation of __cis‐__TiF~4~L~2~. The complex __cis‐__TiF~4~(H~2~O)~2~ and 18‐crown‐6 form [{__

From Molecular to Two-Dimensional Anders
From Molecular to Two-Dimensional Anderson Polyoxomolybdate: Synthesis, Crystal Structure, and Thermal Behavior of [{Ni(H2O)4}2{Ni(OH)6Mo6O18}]·4H2O and [Ni(H2O)6][Ag2{Ni(OH)6Mo6O18}]·8H2O
✍ Feng-Xian Liu; Catherine Marchal-Roch; Damien Dambournet; Aloïs Acker; Jérome Ma 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 739 KB

## Abstract Two 2D Anderson polyoxomolybdate‐based compounds, [{Ni(H~2~O)~4~}~2~{Ni(OH)~6~Mo~6~O~18~}]·4H~2~O (1) and [Ni(H~2~O)~6~][Ag~2~{Ni(OH)~6~Mo~6~O~18~}]·8H~2~O (2), were synthesized and characterized by elemental analysis, IR spectroscopy, SEM, and single‐crystal XRD. Their thermal behavior