18-Crown-6 and Titanium Tetrafluoride −
✍
T. Stanley Cameron; Andreas Decken; Evgeny G. Ilyin; Grigori B. Nikiforov; Jack
📂
Article
📅
2004
🏛
John Wiley and Sons
🌐
English
⚖ 181 KB
👁 1 views
## Abstract Reaction of TiF~4~ and 18‐crown‐6 in MeCN affords the molecular complex [(__cis‐__TiF~4~)~2~(18‐crown‐6)] (1) only. Water and THF displace the 18‐crown‐6 in the tetrafluoro complex 1, with the formation of __cis‐__TiF~4~L~2~. The complex __cis‐__TiF~4~(H~2~O)~2~ and 18‐crown‐6 form [{__