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Stabilization of germanium(IV) aquafluorocompounds in host-guest type complexes with crown ethers. synthesis, crystal structure and ir spectra of the complexes [(GeF5-H2O)2-(H2-1,10-Diaza-l 8-Crown-6)] and [(trans-GeF4· 2H2O) · 18-Crown-6·2H2O]

✍ Scribed by Vladimir O. Gelmboldt; Edward V. Ganin; Larisa V. Ostapchuk; Janusz Lipkowski; Alexander A. Dvorkin; Yurii A. Simonov; Marina S. Fonari


Publisher
Springer Netherlands
Year
1996
Tongue
English
Weight
666 KB
Volume
24
Category
Article
ISSN
0923-0750

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18-Crown-6 and Titanium Tetrafluoride −
✍ T. Stanley Cameron; Andreas Decken; Evgeny G. Ilyin; Grigori B. Nikiforov; Jack 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB 👁 1 views

## Abstract Reaction of TiF~4~ and 18‐crown‐6 in MeCN affords the molecular complex [(__cis‐__TiF~4~)~2~(18‐crown‐6)] (1) only. Water and THF displace the 18‐crown‐6 in the tetrafluoro complex 1, with the formation of __cis‐__TiF~4~L~2~. The complex __cis‐__TiF~4~(H~2~O)~2~ and 18‐crown‐6 form [{__