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Coordination chemistry of macrocyclic polyethers IV X-ray crystal and molecular structure of a host-guest complex of 18-crown-6 with Mn(NO3)2 · 6H2O [MnNO3(H2O)5]+[18-Crown-6]NO3− · H2O

✍ Scribed by Arndt Knöchel; Jürgen Kopf; Joachim Oehler; Gert Rudolph


Publisher
Elsevier Science
Year
1978
Weight
105 KB
Volume
14
Category
Article
ISSN
0020-1650

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A hydrothermal reaction of NaVO 3 , H 3 BO 3 , Zn(CH 3 COO) 2 , ethylenediamine, and H 2 O gives a coordination cluster [Zn(en (denoted on Zn 6 V 12 B 18 ). The Zn 6 V 12 B 18 crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a ‫؍‬ 20.686(3) A s , c ‫؍‬ 20.915(4) A